Search results for "PASSIVE FILMS"
showing 10 items of 19 documents
Physico-chemical characterization of passive films on 316L stainless steel grown in high temperature water
2014
Thermogalvanic corrosion of Alloy 31 in different heavy brine LiBr solutions
2012
Thermogalvanic corrosion generated between two electrodes of Alloy 31, a highly-alloyed austenitic stainless steel (UNS N08031), has been investigated imposing different temperature gradients in three deaerated LiBr solutions, under open circuit conditions by using a zero-resistance ammeter (ZRA). Besides EIS spectra were acquired in order to explain the obtained results. On the whole, cold Alloy 31 electrodes were anodic to hot Alloy 31 electrodes, since an increase in temperature favoured the cathodic behaviour of the hot electrode. Thermogalvanic corrosion of Alloy 31 in the LiBr solutions studied was not severe, although it negatively affects the corrosion resistance of the cold anode. …
Recent advances in using Photocurrent Spectroscopy for the Characterization of Passive Films on Metals and Metallic Alloys
2020
La Spettroscopia a Fotocorrente (PCS) viene qui presentata come tecnica d’indagine non distruttiva, utile per lo studio delle proprietà elettroniche di film passivi accresciuti su metalli e leghe metalliche. In questo lavoro sono stati studiati tramite PCS film passivi di acciai inossidabili quali AISI 304L, AISI 316L e Duplex 2507, accresciuti in soluzione 0.25 M di NaOH a 82°C, condizione simulante l’ambiente aggressivo tipico di operazioni di pulizia nell’industria del food and beverage. Il band gap dei film passivi cambia notevolmente dopo l’immersione per gli acciai 304L e 316L, con un arricchimento in Fe dei film passivi durante il trattamento. Per l’acciaio Duplex invece, il film pas…
Electronic properties and mobile defects distribution in amorphous semiconducting passive films
2003
A study of the electronic properties of thin (drop 25 nm) a-WO3 and a-Nb2O5 is presented. Based on theory of amorphous semiconductor Schottky barrier the fitting of admittance curves in a large range of electrode potential (around 9 V) and a.c. frequency (100 Hz - 10 kHz) is performed. A density of electronic state distribution (DOS) is derived, which mimics the mobile defects distribution suggested by the classical high field model of oxides growth.
Optical modeling of nickel-base alloys oxidized in pressurized water reactor
2012
International audience; The knowledge of the aging process involved in the primary water of pressurized water reactor entails investigating a mixed growth mechanism in the corrosion of nickel-base alloys. A mixed growth induces an anionic inner oxide and a cationic diffusion parallel to a dissolution-precipitation process forms the outer zone. The in situ monitoring of the oxidation kinetics requires the modeling of the oxide layer stratification with the full knowledge of the optical constants related to each component. Here, we report the dielectric constants of the alloys 600 and 690 measured by spectroscopic ellipsometry and fitted to a Drude-Lorentz model. A robust optical stratificati…
Study of Passive Films Formed on AISI 316L Stainless Steel in Non-Polluted and Underwater-Volcano-Polluted Seawater
2014
This work studies the semiconducting behavior of passive films formed on AISI 316L (UNS S31603) in two different sea-water solutions, non-polluted and polluted, collected from the volcano of El Hierro Island. Polarization measurements, potentiostatic passivation tests, electrochemical impedance spectroscopy, and capacitance measurements were performed. Results show that the polluted seawater worsens passivation kinetics. Additionally, passive films formed on AISI 316L stainless steel in polluted seawater have been found to be less protective than those formed in non-polluted seawater, showing a more defective structure, owing to the acidity of the polluted medium.
Photoelectrochemical Techniques in Corrosion Studies
2005
Photocurrent spectroscopy in passivity studies
2018
The aim of this article is to present photocurrent spectroscopy as useful in situ technique for the physicochemical characterization of passive films and corrosion layers. The response of (both amorphous and crystalline) semiconductor/electrolyte junction under irradiation is treated and discussed in order to get information about solid-state properties such as band gap and flat band potential. The possibility to use Photocurrent Spectroscopy (PCS), in a quantitative way, to get information on the composition of corrosion layers is discussed through a semiempirical correlation between the band gap of the oxides (or hydroxides) and the difference of electronegativity of their constituents. F…
Effect of alloying elements on the electronic properties of thin passive films formed on carbon steel, ferritic and austenitic stainless steels in a …
2014
The influence of alloying elements on the electrochemical and semiconducting properties of thin passive films formed on several steels (carbon steel, ferritic and austenitic stainless steels) has been studied in a highly concentrated lithium bromide (LiBr) solution at 25 °C, by means of potentiodynamic tests and Mott Schottky analysis. The addition of Cr to carbon steel promoted the formation of a p-type semiconducting region in the passive film. A high Ni contentmodified the electronic behaviour of highly alloyed austenitic stainless steels.Mo did notmodify the electronic structure of the passive films, but reduced the concentration of defects.
Effect of Composition on the Photoelectrochemical Behavior of Anodic Oxides on Binary Aluminum Alloys
2006
The photoelectrochemical behavior of anodic films on Al alloys, containing titanium, tantalum, and tungsten (valve metals), has been studied as a function of alloy composition and anodizing conditions. Photocurrent spectroscopy has been used to get information on bandgap and the flatband potential values of different mixed oxides. Both insulator-like and semiconducting behavior has been observed for anodic oxides grown on Al-W and Al-Ti alloys dependent on alloy initial composition. Optical bandgap values, E opt g , of different oxides are in accordance with predictions based on the correlation between E opt g and the difference of electronegativities of the oxide constituents, indicating p…